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cis-trans-Isomerisation of the proline-peptide-bond in a cyclic tetrapeptide related to chlamydocin

Cis-trans-Isomerisierung der Prolin-Peptidbindung in einem Derivat von Chlamydocin

  • Organische Chemie Und Biochemie
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Monatshefte für Chemie - Chemical Monthly Aims and scope Submit manuscript

Abstract

Saturation transfer NMR experiments have been used to study the thermodynamic characteristics of the interconversion of two solute conformations of the chlamydocin derivative2 inDMSO-d 6.

Zusammenfassung

Durch Sättigungstransferexperimente wurde die Kinetik der Isomerisierung mittels NMR-Spektroskopie untersucht. Die thermodynamischen Größen der Reaktion wurden bestimmt.

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References

  1. Deber C., Madison V., Blout E. R., Acc. Chem. Res.9, 106 (1976).

    Article  CAS  Google Scholar 

  2. Rich D. H., Bhatnagar P. K., J. Amer. Chem. Soc.100, 2212 (1978).

    Article  CAS  Google Scholar 

  3. Rich D. H., Jasensky R. D., J. Amer. Chem. Soc.101, 5412 (1979).

    Article  CAS  Google Scholar 

  4. Rich D. H., Jasensky R. D., J. Amer. Chem. Soc.102, 1112 (1980).

    Article  CAS  Google Scholar 

  5. Kawai M., Jasensky R. D., Rich D. H., J. Amer. Chem. Soc.105, 4456 (1983).

    Article  CAS  Google Scholar 

  6. Rich D. H., Kawai M., Jasensky R. D., Int. J. Pept. Prot. Res.21, 35 (1983).

    Article  CAS  Google Scholar 

  7. Kessler H., Angew. Chrem.94, 509 (1982).

    Article  CAS  Google Scholar 

  8. Closse A., Huguenin R., Helv. Chim. Acta57, 533 (1974).

    Article  CAS  Google Scholar 

  9. Haslinger E., Kalchhauser H., Tetrahedron Lett.24, 2553 (1983).

    Article  CAS  Google Scholar 

  10. Bystrov V. F., Arseniev A. S., Gawrilov Yu. D., J. Magn. Reson.30, 151 (1978).

    CAS  Google Scholar 

  11. Govil G., Hosur R. V., Conformation of Biological Molecules; New Results from NMR. Berlin-Heidelberg-New York: Springer. 1982.

    Book  Google Scholar 

  12. Hofmann R. A., Forsén S., J. Chem. Phys.45, 2049 (1966).

    Article  Google Scholar 

  13. Noggle J. H., Schirmer R. E., The Nuclear Overhauser Effect; Chemical Applications. New York-London: Academic Press. 1971.

    Google Scholar 

  14. Gerig J. T., Biopolymers10, 2435 (1971).

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Institut für Organische Chemie, Universität Wien, A-1090, Wien, Austria

    Ernst Haslinger & Hermann Kalchhauser

  2. Institut für Theoretische Chemie und Strahlenchemie, Universität Wien, A-1090, Wien, Austria

    Peter Wolschann

Authors
  1. Ernst Haslinger
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  2. Hermann Kalchhauser
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  3. Peter Wolschann
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Additional information

Herrn Prof. Dr.K. Schlögl mit den besten Wünschen zum 60. Geburtstag gewidmet.

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Haslinger, E., Kalchhauser, H. & Wolschann, P. cis-trans-Isomerisation of the proline-peptide-bond in a cyclic tetrapeptide related to chlamydocin. Monatsh Chem 115, 779–783 (1984). https://doi.org/10.1007/BF01120974

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  • DOI: https://doi.org/10.1007/BF01120974

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