Abstract
The vibrational spectra of Tris(trimethylsilyl)phosphane-d 0 and -d 27 as well as Tris(triphenylsilyl)phosphane are reported and assigned. A normal coordinate analysis has been performed. The resulting SiP valence force constants (190 and 200 N/m) are compared with the force constants of other silylphosphanes.
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Hassler, K. Modellrechnungen zu den Schwingungsspektren von Tris(trimethylsilyl)phosphan und Tris(triphenylsilyl)phosphan. Monatsh Chem 115, 713–723 (1984). https://doi.org/10.1007/BF01120966
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DOI: https://doi.org/10.1007/BF01120966