Skip to main content
Log in

Grain boundary precipitation in Magnox AL8O

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Grain boundary precipitates in Magnox ALSO (Mg-0.8% Al) formed after certain heat treatments have been identified as magnesium hydride, MgH2. The solvus temperature for the precipitates was found to be in the range of 300 to 350° C. Ageing at 250° C resulted in overall precipitate growth accompanied by the formation of some grain boundary cavities. Cavities were also formed when hydride precipitates were reheated to higher temperatures. The solvus temperature and the behaviour of the precipitates during ageing at 250° C and subsequent heating to higher temperatures are discussed in terms of the magnesium-hydrogen system.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. E. Harris,Trans. Met. Soc. AIME 233 (1965) 1509.

    Google Scholar 

  2. M. T. Evans, unpublished research (1978).

  3. B. Lisowyj, PhD thesis, University of Leeds (1978).

  4. J. E. Harris,J. Nucl. Mater. 15 (3) (1965) 201.

    Google Scholar 

  5. E. Ross, unpublished research and private communication (1981).

  6. F. H. Ellinger, C. E. Holley, B. B. McInteer, D. Pavonne, R. M. Potter, E. Staritzky andW. H. Zachariasen,J. Amer. Chem. Soc. 77 (1955) 2647.

    Google Scholar 

  7. W. H. Zachariasen, C. E. Holley andJ. F. Stampfer,Acta Crystallogr. 16 (1963) 352.

    Google Scholar 

  8. T. Schober,Met. Trans. 12A (1981) 951.

    Google Scholar 

  9. T. Schober andM. K. Chason,Scripta. Metall. 15 (1981) 791.

    Google Scholar 

  10. Z. D. Popovic andG. R. Piercy,Met. Trans. 6A (1975) 1915.

    Google Scholar 

  11. Y. C. Huang, T. Watanabe andR. Komatsu, in Proceedings of 4th International Conference on Vacuum Metallurgy, Tokyo, 1973 (Iron and Steel Institute of Japan, Tokyo, 1973) p. 176.

    Google Scholar 

  12. J. F. Stampfer, C. E. Holley andJ. F. Suttle,J. Amer, Chem. Soc. 82 (1960) 3504.

    Google Scholar 

  13. E. Fromm andG. Hörz,Int. Met. Rev. 25 (1980) 269.

    Google Scholar 

  14. H. Wenzl,ibid. 27 (1982) 140.

    Google Scholar 

  15. R. Fromageau, C. Mairy andP. Tzanetakis,Scripta Metall. 14 (1980) 395.

    Google Scholar 

  16. E. L. Huston, G. D. Sandrock,J. Less-Common Metals 74 (1980) 435.

    Google Scholar 

  17. P. S. Rudman,Scripta Metall. 14 (1980) 1365.

    Google Scholar 

  18. A. C. Chami, J. P. Bugeat andE. Kigeou,Rad. Eff. 37 (1978) 37.

    Google Scholar 

  19. Z. D. Popovic andM. J. Stott,Phys. Rev. Lett. 33 (1974) 1164.

    Google Scholar 

  20. E. F. Emley, “Principles of Magnesium Technology” (Pergamon, Oxford 1966).

    Google Scholar 

  21. A. E. Vol, “Handbook of binary metallic systems”, Vol. 1 (US Department of Commerce and National Science Foundation, 1967).

  22. J. Rennes andH. J. Grabke,Z. Metallkde 69 (1978) 639.

    Google Scholar 

  23. A. Needleman andJ. R. Rice,Acta Metall. 28 (1980) 1315.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lin, Y.P., Smith, G.C. Grain boundary precipitation in Magnox AL8O. J Mater Sci 23, 2485–2494 (1988). https://doi.org/10.1007/BF01111906

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01111906

Keywords

Navigation