Abstract
The gamma resonance (GR) spectra of a series of π-allylirontricarbonyl compounds and π-cyclopentadienyldicarbonyl complexes of iron have been recorded. The relationship between the GR spectra of these compounds and the electronic structure of the iron atom in the complexes has been examined. It has been shown that tetrahydrofuran, benzene, and acetonitrile do not react with π-allylirontricarbonyl chloride, whereas dimethylformamide decomposes it with the formation of high-spin complexes of iron. The formation of the [π-C3H5Fe(CO3)]− anion in the reduction of [C3H5Fe(CO3)]I by naphthalene-sodium in benzene has been confirmed.
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Borshagovskii, B.V., Gol'danskii, V.I., Gubin, S.P. et al. Gamma resonance spectroscopic study of compounds containing the π-allylirontricarbonyl group. Theor Exp Chem 5, 240–243 (1969). https://doi.org/10.1007/BF01109671
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DOI: https://doi.org/10.1007/BF01109671