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Reaction of acyl isocyanates with pyridine

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The trichloroacetyl and trifluoroacetyl isocyanates react with pyridine to give N-(1-pyridinocarbonyl)trichloro(trifluoro)acetyl amidates, while ditrichloro(trifluoro)acetylcarbodiimides are formed in the presence of 3-phenyl-1-ethyl-3-phospholene 1-oxide, which add to the C = N bond of pyridine on the type of 1,4-cycloaddition.

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Literature cited

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Authors and Affiliations

  1. V. I. Ul'yanov-Lenin Kazan State University, USSR

    B. A. Arbuzov, N. N. Zobova & N. R. Rubinova

Authors
  1. B. A. Arbuzov
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  2. N. N. Zobova
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  3. N. R. Rubinova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 927–928, April, 1977.

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Arbuzov, B.A., Zobova, N.N. & Rubinova, N.R. Reaction of acyl isocyanates with pyridine. Russ Chem Bull 26, 852–853 (1977). https://doi.org/10.1007/BF01108218

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  • DOI: https://doi.org/10.1007/BF01108218

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