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75As NQR spectra of some tetracoordinated arsenic acids

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We were the first to study the NQR spectra of the75As nuclei of a number of alkyl and arylarsonic and arsinic acids. A correlation of the NQR resonance frequencies with the total electronic effects indicates that in the investigated compounds the resonance frequencies are affected mainly by the inductive effects of the substituents.

  2. 2.

    In the given series of compounds the NQR frequency of the75As nuclei decrease with decrease in the difference of the populations of the equivalent (nc) and nonequivalent (n a , nb) bonds attached to the resonance atom.

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Authors and Affiliations

  1. Kazan Physicotechnical Institute, Kazan Branch of the Academy of Sciences of the USSR, USSR

    D. U. Zakirov, V. I. Savdur, V. S. Gamayurova, B. D. Chernokal'skii & I. A. Safin

  2. S. M. Kirov Kazan Chemicotechnological Institute, USSR

    D. U. Zakirov, V. I. Savdur, V. S. Gamayurova, B. D. Chernokal'skii & I. A. Safin

Authors
  1. D. U. Zakirov
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  2. V. I. Savdur
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  3. V. S. Gamayurova
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  4. B. D. Chernokal'skii
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  5. I. A. Safin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 910–912, April, 1977.

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Zakirov, D.U., Savdur, V.I., Gamayurova, V.S. et al. 75As NQR spectra of some tetracoordinated arsenic acids. Russ Chem Bull 26, 834–836 (1977). https://doi.org/10.1007/BF01108211

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  • DOI: https://doi.org/10.1007/BF01108211

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