Tetracarbonyliron π complexes of β-iodovinyl ketones and esters of β-iodoacrylic acid and their reactions with the dicarbonyl-π-cyclopentadienyliron dimer

Bulletin of the Academy of Sciences of the USSR, Division of chemical science volume 26, pages828–831(1977)Cite this article

Conclusions

  1. 1.

    The reaction of methyl β-iodovinyl ketone and esters of β-iodoacrylic acid with Fe2(CO)9 produced their tetracarbonyliron π complexes.

  2. 1.

    The iodine atom in the complexes (RCOCH = CHI) [Fe(CO)4] (R = Me, MeO) is capable of being replaced by a CpFe(CO)2 group to form hexylcarbonyldiiron complexes.

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Literature cited

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Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. N. Nesmeyanov, M. I. Rybinskaya, L. V. Rybin, E. A. Petrovskaya & A. I. Lutsenko

Authors
  1. A. N. Nesmeyanov
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  2. M. I. Rybinskaya
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  3. L. V. Rybin
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  4. E. A. Petrovskaya
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  5. A. I. Lutsenko
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 904–907, April, 1977.

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Nesmeyanov, A.N., Rybinskaya, M.I., Rybin, L.V. et al. Tetracarbonyliron π complexes of β-iodovinyl ketones and esters of β-iodoacrylic acid and their reactions with the dicarbonyl-π-cyclopentadienyliron dimer. Russ Chem Bull 26, 828–831 (1977). https://doi.org/10.1007/BF01108209

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Keywords

  • Methyl
  • Ester
  • Iodine
  • Ketone
  • Iodine Atom