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Catalytic hydrocondensation of carbon monoxide with olefins and their hydropolymerization on exposure to carbon monoxide and hydrogen

55. Hydropolymerization of lower olefins in the presence of Co-ZrO2 AND Co-TiO2 catalysts

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Co-ZrO2 and Co-TiO2 catalysts are active in hydropolymerization reactions of lower olefins initiated with CO at temperatures of 180–190°. The catalytic activities depend on the method of their preparation.

  2. 2.

    The reactivity of olefins on the studied catalysts decreases in the series: C2H4 > C3H6 > n-C4H8 > i-C4H8.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. L. Lapidus, I. V. Guseva, V. I. Mashinskii & Ya. T. Éidus

Authors
  1. A. L. Lapidus
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  2. I. V. Guseva
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  3. V. I. Mashinskii
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  4. Ya. T. Éidus
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya, Khimicheskaya, No. 4, pp. 825–828, April, 1977.

See [1] for Communication 54.

Deceased.

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Lapidus, A.L., Guseva, I.V., Mashinskii, V.I. et al. Catalytic hydrocondensation of carbon monoxide with olefins and their hydropolymerization on exposure to carbon monoxide and hydrogen. Russ Chem Bull 26, 750–753 (1977). https://doi.org/10.1007/BF01108193

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  • DOI: https://doi.org/10.1007/BF01108193

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