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Carbonylation of aliphatic and cyclic alcohols by carbon monoxide in the presence of complexes of BF3 with acetic, propionic, or monochloroacetic acid

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The complexes BF3-2CH3CH2COOH and BF3·2CH3COOH and the system 3BF3·2CH2ClCOOH-BF3·2CH3-COOH are active and stable catalysts of the carbonylation reaction (80–100°, pCO=100 atm) of tertiary and secondary alcohols of aliphatic and cyclic structure with formation of carboxylic acids in high yields and can be used repeatedly without a decrease in the initial activity.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    S. D. Pirozhkov, K. V. Puzitskii, T. N. Myshenkova, K. G. Ryabova & Ya. T. Éidus

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  1. S. D. Pirozhkov
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  2. K. V. Puzitskii
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  3. T. N. Myshenkova
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  4. K. G. Ryabova
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  5. Ya. T. Éidus
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 817–825, April, 1977.

Deceased.

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Pirozhkov, S.D., Puzitskii, K.V., Myshenkova, T.N. et al. Carbonylation of aliphatic and cyclic alcohols by carbon monoxide in the presence of complexes of BF3 with acetic, propionic, or monochloroacetic acid. Russ Chem Bull 26, 744–750 (1977). https://doi.org/10.1007/BF01108192

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  • DOI: https://doi.org/10.1007/BF01108192

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