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Electrochemical reduction ofα,β-unsaturated diphosphonium salts on a mercury electrode

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Study has been made of the electrochemical reduction of the salts of trans-1,2-diphosphonioethene on the dropping Hg electrode in protogenic and aprotic media.

  2. 2.

    It has been shown that stable radical anions result from the first, reversible one-electron stage of the reduction of disalts in aprotic media. A scheme is proposed to describe the reduction mechanism.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    E. A. Berdnikov, F. R. Tantasheva, V. I. Morozov, A. V. Il'yasov & A. A. Vafina

  2. V. I. Ul'yanov-Lenin Kazan State University, USSR

    E. A. Berdnikov, F. R. Tantasheva, V. I. Morozov, A. V. Il'yasov & A. A. Vafina

Authors
  1. E. A. Berdnikov
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  2. F. R. Tantasheva
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  3. V. I. Morozov
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  4. A. V. Il'yasov
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  5. A. A. Vafina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 803–807, April, 1977.

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Berdnikov, E.A., Tantasheva, F.R., Morozov, V.I. et al. Electrochemical reduction ofα,β-unsaturated diphosphonium salts on a mercury electrode. Russ Chem Bull 26, 731–735 (1977). https://doi.org/10.1007/BF01108190

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  • DOI: https://doi.org/10.1007/BF01108190

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