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Anisotropy of polarizability of the silatranes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Polarizability parameters have been determined for the Si-C and Si-O bonds. The Si-O bond of the siloxanes does not show axial symmetry.

  2. 2.

    The axes of the molecular polarizability ellipsoid for 1-methylsilatrane have been determined.

  3. 3.

    The transannular N → Si bond shows a pronounced anisotropy of polarizability in the silatranes.

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Authors and Affiliations

  1. V. I. Ul'yanov-Lenin Kazan State University, USSR

    O. A. Samarina, A. N. Vereshchagin, É. A. Ishmaeva, S. G. Vul'fson, V. M. D'yakov, V. P. Baryshok, M. G. Voronkov & A. N. Pudovik

  2. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    O. A. Samarina, A. N. Vereshchagin, É. A. Ishmaeva, S. G. Vul'fson, V. M. D'yakov, V. P. Baryshok, M. G. Voronkov & A. N. Pudovik

  3. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    O. A. Samarina, A. N. Vereshchagin, É. A. Ishmaeva, S. G. Vul'fson, V. M. D'yakov, V. P. Baryshok, M. G. Voronkov & A. N. Pudovik

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  1. O. A. Samarina
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  2. A. N. Vereshchagin
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  3. É. A. Ishmaeva
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  4. S. G. Vul'fson
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  5. V. M. D'yakov
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  6. V. P. Baryshok
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  7. M. G. Voronkov
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  8. A. N. Pudovik
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 785–791, April, 1977.

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Samarina, O.A., Vereshchagin, A.N., Ishmaeva, É.A. et al. Anisotropy of polarizability of the silatranes. Russ Chem Bull 26, 713–719 (1977). https://doi.org/10.1007/BF01108187

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  • DOI: https://doi.org/10.1007/BF01108187

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