Conclusions
The reaction of 2,6-di-tert-butyl-1,4-benzoquinonediazide with primary aliphatic amines leads to the formation of intermediate unstable triazenes which, in turn, break down through a radical mechanism to form 2,6-di-tert-butylphenol and 2,6-di-tert-butyl-p-benzoquinone, the final reaction products.
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Sh. A. Markaryan, L. G. Plekhanova, G. A. Nikiforov, S. V. Rykov, V. V. Ershov and A. L. Buchachenko, Izv. Akad. Nauk SSSR, Ser. Khim., 2620 (1972).
G. A. Nikiforov, A. A. Efremenko and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 2702 (1967).
G. A. Nikoforov, L. G. Plekhanova, A. A. Efremenko, D. G. Pobedimskii and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 146 (1971).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 771–775, April, 1977.
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Nikiforov, G.A., Pershin, A.D., Kende, I. et al. Chemical polarization of nuclei. Russ Chem Bull 26, 700–704 (1977). https://doi.org/10.1007/BF01108184
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DOI: https://doi.org/10.1007/BF01108184