Skip to main content
SpringerLink
Log in

ESR investigation of proton transfer from 3,6-di-tert-butyl-2-hydroxyphenoxyl to primary and secondary amines

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The authors have investigated the reversible transfer of a proton from the hydroxyl group of 3,6-di-tert-butyl-2-hydroxyphenoxyl to diethylamine.

  2. 2.

    They have discovered and investigated proton exchange between the radical and primary and secondary amines. On the basis of the experimental data they suggested a mechanism for this exchange, involving the semiquinone radical anion as an intermediate compound.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. I. Prokof'ev, N. N. Bubnov, S. P. Solodovnikov, and M. I. Kabachnik, Izv. Akad. Nauk SSSR, Ser. Khim., 2213 (1974).

  2. A. S. Masalimov, A. I. Prokof'ev, N. N. Bubnov, S. P. Solodovnikov, and M. I. Kabachnik, Izv. Akad. Nauk SSSR, Ser. Khim., 190 (1976).

  3. A. S. Masalimov, A. I. Prokof'ev, N. N. Bubnov, S. P. Solodovnikov, and M. I. Kabachnik, Izv. Akad. Nauk SSSR, Ser. Khim., 193 (1976).

  4. A. I. Prokof'ev, N. N. Bubnov, S. P. Solodovnikov, I. S. Belostotskaya, V. V. Ershov, and M. I. Kabachnik, Izv. Akad. Naus SSSR, Ser. Khim., 2467 (1974).

  5. A. Carrington and McLachlan, Introduction to Magnetic Resonance with Applications to Chemistry and Chemical Physics, Harper-Row (1967).

  6. I. S. Belostotskaya, N. L. Komissarova, É. V. Dzhuraryan, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 1594 (1972).

  7. N. L. Komissarova, I. S. Belostotskaya, É. V. Dzhuaryan, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 1380 (1973).

Download references

Author information

Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. S. Masalimov, A. I. Prokof'ev, N. N. Bubnov, S. P. Solodvnikov & M. I. Kabachnik

Authors
  1. A. S. Masalimov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. I. Prokof'ev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. N. Bubnov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. P. Solodvnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. I. Kabachnik
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 767–771, April, 1977.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Masalimov, A.S., Prokof'ev, A.I., Bubnov, N.N. et al. ESR investigation of proton transfer from 3,6-di-tert-butyl-2-hydroxyphenoxyl to primary and secondary amines. Russ Chem Bull 26, 696–700 (1977). https://doi.org/10.1007/BF01108183

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01108183

Keywords

Search

Navigation