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Diethylarsine benzoate radical anions

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Arsinobenzoates are reduced in three steps, the first of which involves one electron and is reversible. The diethylarsinyl groups are electron acceptors. Transfer of a second electron leads to the rupture of the As-C bond and to the formation of methyl benzoate.

  2. 2.

    The spin-density distribution in the arsinobenzoate radical anions has been studied.

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Literature cited

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, USSR

    A. V. Il'yasov, B. D. Chernokal'skii, A. S. Gel'fond, A. A. Vafina, A. A. Barlev & Yu. G. Galyametdinov

  2. S. M. Kirov Kazan Chemical Technology Institute, Kazan Branch of the Academy of Sciences of the USSR, USSR

    A. V. Il'yasov, B. D. Chernokal'skii, A. S. Gel'fond, A. A. Vafina, A. A. Barlev & Yu. G. Galyametdinov

Authors
  1. A. V. Il'yasov
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  2. B. D. Chernokal'skii
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  3. A. S. Gel'fond
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  4. A. A. Vafina
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  5. A. A. Barlev
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  6. Yu. G. Galyametdinov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 684–686, March, 1976.

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Il'yasov, A.V., Chernokal'skii, B.D., Gel'fond, A.S. et al. Diethylarsine benzoate radical anions. Russ Chem Bull 25, 672–674 (1976). https://doi.org/10.1007/BF01106682

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  • DOI: https://doi.org/10.1007/BF01106682

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