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Germylation reaction of phenoxyacetylene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The metallation process dominates in reaction of (C2H5)3GeLi with phenoxyacetylene, leading to C6H5OC=CLi. Addition at the acetylene bond proceeds nonregiospecifically with formation of α- and cisβ-adducts.

  2. 2.

    Addition of (C2H5)3GeH to phenoxyacetylene under the effect of Spaier catalyst leads to a mixture of α-, cis-β-, and trans-β-adducts.

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Literature cited

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    O. A. Kruglaya, G. S. Lyashenko, A. Kh. Filippova, V. V. Keiko, I. D. Kalikhman & N. S. Vyazankin

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  1. O. A. Kruglaya
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  2. G. S. Lyashenko
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  3. A. Kh. Filippova
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  4. V. V. Keiko
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  5. I. D. Kalikhman
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  6. N. S. Vyazankin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 682–683, March, 1976.

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Kruglaya, O.A., Lyashenko, G.S., Filippova, A.K. et al. Germylation reaction of phenoxyacetylene. Russ Chem Bull 25, 669–671 (1976). https://doi.org/10.1007/BF01106681

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  • DOI: https://doi.org/10.1007/BF01106681

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