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Mass-spectrometric study of negative ion formation in the series of π,π-complexes of titanium

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The effect was studied of the nature of the substituent on the titanium atom on the mechanism of decomposition of molecular negative ions of compounds TiCl4, (C2H5)2TiCl2, [C5H4Si(CH3 2]2TiCl2, (C5H5)2-Ti(CH3)2, [C5H4Si(CH3)3]2Ti(CH3)2, TiCl Al(i-C4H9)3, and Al(i-C4H9)3. Average lifetimes of molecular negative ions of the indicated compounds were measured.

  2. 2.

    The existence of long-lived molecular negative ions of the studied titanium derivatives showed that all of them, including tetrahalides, have positive affinity for an electron.

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Literature cited

  1. S. L. Bennett, R. E. Pabst, J. L. Margrawe, and J. L. Franklin, Inter. J. Mass-Spectrom. Jon. Phys.,15, 451 (1974).

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  2. J. G. Dillard, Chem. Rev.,73, 589 (1973).

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Authors and Affiliations

  1. Bashkir Branch of the Academy of Sciences of the USSR, Institute of Chemistry, Ufa

    A. Sh. Sultanov, U. M. Dzhemilev, M. S. Miftakhov, V. I. Khvostenko & G. A. Tolstikov

Authors
  1. A. Sh. Sultanov
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  2. U. M. Dzhemilev
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  3. M. S. Miftakhov
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  4. V. I. Khvostenko
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  5. G. A. Tolstikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 673–675, March, 1976.

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Sultanov, A.S., Dzhemilev, U.M., Miftakhov, M.S. et al. Mass-spectrometric study of negative ion formation in the series of π,π-complexes of titanium. Russ Chem Bull 25, 660–661 (1976). https://doi.org/10.1007/BF01106678

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  • DOI: https://doi.org/10.1007/BF01106678

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