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Manifestation of orientational vibrations in the ESR spectrum of vanadyl acetylacetonate

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The observed change, with change in temperature, in the components of the tensor of the hyperfine interaction and in the relative intensity of the corresponding ESR lines is due to the anisotropic vibrational motion.

  2. 2.

    The observed anisotropy of the motion makes it possible to relate the values of the magnetic parameters to the molecular axes of the complex in nonoriented systems.

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Literature cited

  1. D. Kivelson and S. Lee, J. Chem. Phys.,41., 1896 (1964).

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  2. N. N. Korst and A. V. Lazarev, Physika,42, 31 (1969); S. A. Goldman, G. V. Bruno, C. F. Polnaszek, and I. H. Freed, J. Chem. Phys.,56, 716 (1972).

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Authors and Affiliations

  1. Physicotechnical Institute, Kazan' Branch, Academy of Sciences of the USSR, USSR

    I. G. Bikchantaev & I. V. Ovchinnikov

Authors
  1. I. G. Bikchantaev
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  2. I. V. Ovchinnikov
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Additional information

Translated from Izvestiya Asademii Nauk SSSR, No. 3, pp. 657–659, March, 1976.

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Bikchantaev, I.G., Ovchinnikov, I.V. Manifestation of orientational vibrations in the ESR spectrum of vanadyl acetylacetonate. Russ Chem Bull 25, 641–643 (1976). https://doi.org/10.1007/BF01106671

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  • DOI: https://doi.org/10.1007/BF01106671

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