Conclusions
In the electrochemical reduction of 2,6-dinitro-4R-anisole (R = COO−, OCH3, H, Cl) in DMSO-CH3OH, the formation of anion radicals of the initial anisoles and AR of the corresponding 2-nitroso-4R-6-nitroanisoles was demonstrated. The structure was established, and a mechanism was proposed for the formation of anion radicals of these nitroso compounds.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3,pp. 520–526, March, 1976.
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Starichenko, V.F., Ryabinin, V.A. & Shein, S.M. Electrochemical generation of anion radicals of nitroso and nitro compounds from substituted 2,6-dinitroanisoles. Russ Chem Bull 25, 503–508 (1976). https://doi.org/10.1007/BF01106641
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DOI: https://doi.org/10.1007/BF01106641