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Electrochemical generation of anion radicals of nitroso and nitro compounds from substituted 2,6-dinitroanisoles

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

In the electrochemical reduction of 2,6-dinitro-4R-anisole (R = COO−, OCH3, H, Cl) in DMSO-CH3OH, the formation of anion radicals of the initial anisoles and AR of the corresponding 2-nitroso-4R-6-nitroanisoles was demonstrated. The structure was established, and a mechanism was proposed for the formation of anion radicals of these nitroso compounds.

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Authors and Affiliations

  1. Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    V. F. Starichenko, V. A. Ryabinin & S. M. Shein

Authors
  1. V. F. Starichenko
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  2. V. A. Ryabinin
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  3. S. M. Shein
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3,pp. 520–526, March, 1976.

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Starichenko, V.F., Ryabinin, V.A. & Shein, S.M. Electrochemical generation of anion radicals of nitroso and nitro compounds from substituted 2,6-dinitroanisoles. Russ Chem Bull 25, 503–508 (1976). https://doi.org/10.1007/BF01106641

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  • DOI: https://doi.org/10.1007/BF01106641

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