Skip to main content
SpringerLink
Log in

Investigation of fast reactions of sterically hindered aroxyl radicals

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A method is proposed for investigating fast reactions of aroxyl radicals. The kinetic parameters obtained for the reaction of 2,4,6-tri-t-butylphenoxyl with phenol and with 4-bromophenol coincide with the data obtained by other methods.

  2. 2.

    From an analysis of the kinetic data, it is concluded that the OH bond energy in 4-methyl-2,6-di-t-butylphenol is close to that in 2,4,6-tri-t-butylphenol.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. L. Buchachenko, Stable Radicals [in Russian], Nauka (1963).

  2. V. D. Pokhodenko, Phenoxyl Radicals [in Russian], Naukova Dumka, Kiev (1969).

    Google Scholar 

  3. A. R. Forrester, S. M. Hay, and R. H. Thomson, Organic Chemistry of Stable Free Radicals, New York (1968).

  4. V. D. Pokhodenko, V. A. Khizhnyi, and V. A. Bidzilya, Uspekhi Khim.,37, 998 (1968).

    Google Scholar 

  5. A. L. Buchachenko and A. M. Vasserman, Stable Eadicals [in Russian], Khimiya (1973).

  6. M. A. DaRooge and L. R. Mahoney, J. Org. Chem.,32, 1 (1967).

    Google Scholar 

  7. L. R. Mahoney, F. C. Ferris, and M. A. DaRooge, J. Amer. Chem. Soc.,89, 1895, 5619 (1967);91, 3883 (1969);92, 890 (1970).

    Google Scholar 

  8. N. N. Bubnov, S. G. Kukes, A. I. Prokof'ev, S. P. Solodovnikov, and M. I. Kabachnik, Dokl. Akad. Nauk SSSR,214, 1319 (1974).

    Google Scholar 

  9. E. T. Denisov, Uspekhi Khim.,42, 361 (1973).

    Google Scholar 

  10. S. P. Solodovnikov and A. I. Prokof'ev, Dokl. Akad. Nauk SSSR,180, 158 (1968).

    Google Scholar 

  11. A. I. Prokof'ev, S. P. Solodovnikov, G. A. Nikiforov, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 558 (1970).

  12. V. A. Bidzilya, V. D. Pokhodenko, and A. I. Brodskii, Dokl. Akad. Nauk SSSR,166, 1099 (1966).

    Google Scholar 

  13. R. Kreilick and S. Weissman, J. Amer. Chem. Soc.,84, 306 (1962).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. I. Prokof'ev, N. A. Malysheva, N. N. Bubnov, S. P. Solodovnikov & M. I. Kabachnik

Authors
  1. A. I. Prokof'ev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. A. Malysheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. N. Bubnov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. P. Solodovnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. I. Kabachnik
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 511–515, March, 1976.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Prokof'ev, A.I., Malysheva, N.A., Bubnov, N.N. et al. Investigation of fast reactions of sterically hindered aroxyl radicals. Russ Chem Bull 25, 494–497 (1976). https://doi.org/10.1007/BF01106639

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01106639

Keywords

Search

Navigation