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Conclusions

  1. 1.

    Oxygen diffusing through a silver membrane catalyst is more active in the formation of products of the complete oxidation of ethylene than oxygen introduced in a mixture with ethylene.

  2. 2.

    The permeability of silver to oxygen passes through a minimum with increasing ethylene pressure at the output surface of the silver membrane and reaches a value equal to the permeability in the case of diffusion into vacuum.

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Literature cited

  1. V. M. Gryaznov, Kinet. Katal.12, 640 (1971).

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  2. V. M. Gryaznov, V. S. Smirnov, L. K. Ivanova, and A. P. Mishchenko, Dokl. Akad. Nauk SSSR,190, 144 (1970).

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  3. V. M. Gryaznov, S. G. Gul'yanova, and S. Kanizius, Zh. Fiz. Khim.,47, 2694 (1973).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 508–11, March, 1976.

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Gryaznov, V.M., Smirnov, V.S., Gul'yanova, S.G. et al. Conversions of ethylene on a silver membrane catalyst. Russ Chem Bull 25, 490–493 (1976). https://doi.org/10.1007/BF01106638

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  • DOI: https://doi.org/10.1007/BF01106638

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