Conclusions
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1.
Oxygen diffusing through a silver membrane catalyst is more active in the formation of products of the complete oxidation of ethylene than oxygen introduced in a mixture with ethylene.
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2.
The permeability of silver to oxygen passes through a minimum with increasing ethylene pressure at the output surface of the silver membrane and reaches a value equal to the permeability in the case of diffusion into vacuum.
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V. M. Gryaznov, Kinet. Katal.12, 640 (1971).
V. M. Gryaznov, V. S. Smirnov, L. K. Ivanova, and A. P. Mishchenko, Dokl. Akad. Nauk SSSR,190, 144 (1970).
V. M. Gryaznov, S. G. Gul'yanova, and S. Kanizius, Zh. Fiz. Khim.,47, 2694 (1973).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 508–11, March, 1976.
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Gryaznov, V.M., Smirnov, V.S., Gul'yanova, S.G. et al. Conversions of ethylene on a silver membrane catalyst. Russ Chem Bull 25, 490–493 (1976). https://doi.org/10.1007/BF01106638
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DOI: https://doi.org/10.1007/BF01106638