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Investigation of polyfunctional zeolite catalysts

Communication 2. Formation of a catalyst for the synthesis of sec-butylbenzene, produced from nickel acetate and CaY zeolite

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    By an investigation of the catalytic properties and IR spectra of samples subjected to various treatment, it was established that bifunctional catalysts, effective in the synthesis of secondary butylbenzene from benzene and ethylene, are formed from the system nickel acetylacetonate — CaY zeolite in the process of heat treatment in an oxidizing medium (O2, air) at the temperatures 400–500°.

  2. 2.

    The dimerization of ethylene proceeds with the participation of nickel ions, arising in the interaction of NiO, formed from Ni acetylacetonate, with the proton acid centers of the zeolite.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    Ya. I. Isakov, Kh. M. Minachev & V. P. Kalinin

Authors
  1. Ya. I. Isakov
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  2. Kh. M. Minachev
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  3. V. P. Kalinin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 498–504, March, 1976.

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Isakov, Y.I., Minachev, K.M. & Kalinin, V.P. Investigation of polyfunctional zeolite catalysts. Russ Chem Bull 25, 481–485 (1976). https://doi.org/10.1007/BF01106636

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  • DOI: https://doi.org/10.1007/BF01106636

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