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Chlorine fluorosulfate

Communication 4. Reactions with certain derivatives of nitro compounds

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Under mild conditions chlorine fluorosulfate chlorinates salts of nitro compounds, replaces the carbethoxy and methylol groups in polynitro derivatives by a chlorine atom, and, depending on the structures of nitro-containing nitriles, either replaces the nitrile group by a chlorine atom or adds on at the C≡N bond.

  2. 2.

    Treatment of hydrogen-containing nitromethanes or their salts with peroxydisulfuryl difluoride gave nitromethyl esters of fluorosulfonic acid.

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Authors
  1. A. V. Fokin
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  2. Yu. N. Studnev
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  3. A. I. Rapkin
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  4. L. D. Kuznetsova
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  5. V. A. Komarov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 489–492, March, 1976.

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Fokin, A.V., Studnev, Y.N., Rapkin, A.I. et al. Chlorine fluorosulfate. Russ Chem Bull 25, 472–475 (1976). https://doi.org/10.1007/BF01106634

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  • DOI: https://doi.org/10.1007/BF01106634

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