Conclusions
-
1.
Using the chemical shifts of the Kα1 x-ray lines of Ag and the method of layerwise solution, the authors have investigated the reaction kinetics of the products of sorption of gallium by silver sulfide with a twofold excess of gallium in solution in relation to the stoichiometry.
-
2.
In the initial stage of sorption of gallium by silver sulfide, two forms appear: the primary form, 2Ag2S · Ga2S3, and the final form, Ag4Ga2S5.
-
3.
If the solid phase is in contact with the solution, the primary form is converted to the stable final form within 32 h.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
L. L. Makarov, N. A. Rudnev, I. V. Melikhov, A. M. Tuzova, and Yu. M. Zaitsev, Dokl. Akad. Nauk SSSR,209, 893 (1973).
N. A. Rudnev, Progress in Analytical Chemistry [in Russian], Nauka (1974), p. 236.
L. L. Makarov, Yu. P. Kostikov, G. P. Shabanova, and A. V. Panin, Transactions of International Symposium on X-Ray Spectra and the Electron Structure of Matter, [in Russian], Kiev (1968), p. 264.
N. A. Rudnev, A. M. Tuzova, and G. I. Malofeeva, Zh. Analiticheskoi Khim.,26, 886 (1971).
N. A. Rudnev and G. I. Malofeeva, Zh. Neorgan. Khim.,8, 1770 (1963).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSR, Seriya Khimicheskaya, No. 3, pp. 487–489, March, 1976.
Rights and permissions
About this article
Cite this article
Tuzova, A.M., Makarov, L.L., Rudnev, N.A. et al. Use of the chemical shifts of the Kα1 X-ray line of47Ag to study the mechanism of sorption of gallium by silver sulfide. Russ Chem Bull 25, 469–471 (1976). https://doi.org/10.1007/BF01106633
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01106633