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Pauling's second crystal rule for nitrogen-substituted crystal structures

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Abstract

The use of Pauling's second crystal rule possibly for predicting anion aliovalent substitutions, particularly those of nitrogen replacing oxygen, in crystallographic isotypes is examined. Bond length/bond strength sums are also reviewed for some structures where nitrogen-substitution is known.

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Morgan, P.E.D. Pauling's second crystal rule for nitrogen-substituted crystal structures. J Mater Sci 21, 4305–4309 (1986). https://doi.org/10.1007/BF01106546

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