Abstract
The frequencies of the spectra of aqueous and nonaqueous solutions of a number of uranyl salts were analyzed. The previous assignment of the frequency of 200 cm−1 to the deformational vibrations of the uranyl ion [1] was confirmed. The activity of this frequency in the Raman spectrum is determined by the structure of the complex compounds.
Similar content being viewed by others
References
G. K. T. Conn and C. K. Wu, Trans. Farad. Soc.,34, 1483, 1938.
H. D. Bist and D. D. Pant, Indian J. Pure and Appl. Phys.,2, 107, 1964.
G. H. Dieke and A. B. F. Duncan, Spectroscopic Properties of Uranium Compounds, McGraw-Hill, New York, 1949.
B. S. Satyanarayana, Proc. Ind. Acad. Sci.,15A, 414, 1942.
H. W. Crandall, J. Chem. Phys.,17, 602, 1949.
J. Sutton, Nature,169, 235, 1952.
S. Mints and Z. Kentskii, Izv. AN SSSR, ser. fiz.,23, 1182, 1959.
A. N. Sevchenko and B. I. Stepanov, ZhETF,19, 1113, 1949.
B. M. Gatehouse and A. E. Comyns, J. Chem. Soc., 3965, 1958.
L. I. Katzin and J. C. Sullivan, J. Phys. Coll. Chem.,55, 346, 1951.
L. V. Volod'ko, Trudy Instituta Fiziki i Matematiki AN BSSR, no. 2, 174, 1957.
S. P. McGlynn, J. K. Smith, and W. C. Neely, J. Chem. Phys., 35, 105, 1961.
K. W. F. Kohlraush, Ramanspektren, Ann Arbor, 1944.
G. Herzberg, Infrared and Raman Spectra of Polyatomic Molecules, Van Nostrand, New York, 1945.
V. M. Vdovenko, D. N. Suglobov, and V. A. Krasu'nikov, in collection: Physical Problems of Spectroscopy [in Russian], Izd. AN SSSR, Moscow, vol. 1, p. 240, 1962.
L. V. Volod'kov and A. N. Sevchenko, Opt. i spektr.,4, 47, 1958.
H. T. Evans, Science,141, 54, 1963.
I. I. Lipilina, Uranyl and Its Compounds [in Russian], Izd. AN SSSR, Moscow, 1959.
Rights and permissions
About this article
Cite this article
Volod'ko, L.V., Sabilo, K.V. Raman spectra of solutions of uranyl compounds. J Appl Spectrosc 4, 39–42 (1966). https://doi.org/10.1007/BF01106199
Issue Date:
DOI: https://doi.org/10.1007/BF01106199