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Characterization of converted tin phosphate coating on iron and steel by conversion electron Mössbauer spectrometry (CEMS)

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Abstract

The chemical states of tin in converted tin phosphate coatings on iron and steel and in tin phosphate powders were analysed by conversion electron Mössbauer spectrometry and transmission Mössbauer spectrometry. The tin species in stannous phosphate, stannic oxide and metallic tin were recognized in the converted tin phosphate coatings. Mössbauer parameters of Sn(II) included in the phosphate coatings were slightly different from those of Sn(II) incorporated in powders of zinc and manganese phosphate compounds. The tin atoms mainly occupied two different sites in three sites of stannous phosphate structure, depending on the preparations.

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References

  1. G. Lorin, “Phosphating of metals” (Finishing Publications Ltd, Middlesex, 1974).

    Google Scholar 

  2. M. Gebhardt,Farb und Lack 73 (1968) 217.

    Google Scholar 

  3. K. Nomura, Y. Ujihira, Y. Matsushima, R. Kojima andY. Sugawara,Nippon Kagakukai-shi (1980) 1372.

  4. K. Nomura andY. Ujihira,J. Anal. Appl. Pyrol. 5 (1983) 221.

    Google Scholar 

  5. K. Nomura, Y. Ujihira andR. Kojima,Nippon Kagakukai-shi (1982) 87.

  6. K. Nomura andY. Ujihira,ibid. (1982) 1352.

  7. Idem, J. Mater. Sci. 17 (1982) 3437.

    Google Scholar 

  8. E. Mattievich andJ. Danon,J. Inorg. Nucl. Chum. 39 (1977) 569.

    Google Scholar 

  9. B. S. Tuttle andT. Novoy, US Pat 2 478 954, 16 August 1949.

  10. T. Oyagi,Boseikanri 5(6) (1961) 17.

    Google Scholar 

  11. K. Nomura andY. Ujihira,Bunsekikagaku 33 (1984) T81.

    Google Scholar 

  12. R. C. Mercader, E. J. Baran andA. R. Lopez-Garcia,J. Radioanal. Nucl. Chem. Lett. 85 (1984) 13.

    Google Scholar 

  13. J. M. Friedt andY. Llabador,Radiochem. Radioanal. Nucl. Chem. Lett. 9 (1972) 237.

    Google Scholar 

  14. J. K. Lees andP. A. Flinn,J. Chem. Phys. 48 (1968) 882.

    Google Scholar 

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Authors and Affiliations

  1. Faculty of Engineering, The University of Tokyo, Hongo 7-3-1, Bunkyo-ku, 113, Tokyo, Japan

    K. Nomura & Y. Ujihira

  2. Central Research Laboratories, Nihon Parkerizing Co. Ltd, Ogami 2784, 254, Hiratsuka City, Kanagawa Prefecture, Japan

    R. Kojima & M. Yoshida

Authors
  1. K. Nomura
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  2. Y. Ujihira
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  3. R. Kojima
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  4. M. Yoshida
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Nomura, K., Ujihira, Y., Kojima, R. et al. Characterization of converted tin phosphate coating on iron and steel by conversion electron Mössbauer spectrometry (CEMS). J Mater Sci 27, 2449–2457 (1992). https://doi.org/10.1007/BF01105057

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  • DOI: https://doi.org/10.1007/BF01105057

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