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Intramolecular cyclization of β-chloroethyl perfluoroalkenyl ethers by fluoride ion

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

β-Chloroethyl perfluoroalkenyl ethers are capable of reversibly adding fluoride ion, generating alkoxy-substituted carbanions that are stabilized via the intramolecular nucleophilic replacement of chlorine atom to give heterocyclic compounds.

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Literature cited

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. F. Snegirev, L. L. Gervits, K. N. Makarov & I. L. Knunyants

Authors
  1. V. F. Snegirev
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  2. L. L. Gervits
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  3. K. N. Makarov
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  4. I. L. Knunyants
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2641–2643, November, 1981.

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Snegirev, V.F., Gervits, L.L., Makarov, K.N. et al. Intramolecular cyclization of β-chloroethyl perfluoroalkenyl ethers by fluoride ion. Russ Chem Bull 30, 2197–2199 (1981). https://doi.org/10.1007/BF01094663

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  • DOI: https://doi.org/10.1007/BF01094663

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