Skip to main content
SpringerLink
Log in

Reaction of 2-acetyl-3-methoxy-5-methyldiazaphospholine with p-toluenesulfonyl azide

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Tosyl azide reacts with 2-acetyl-3-methoxy-5-methyldiazaphospholine to give an iminodiazaphospholine that is stable as a solid, while in solutions, depending on the nature of the solvent and the temperature, it changes to the tautomer with an NH bond and the dimer. The equilibrium interconversion of these three forms was shown on the basis of the IR and31P NMR spectra.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literature cited

  1. B. A. Arbuzov and É. N. Dianova, Dokl. Akad. Nauk SSSR,255, 1117 (1980).

    Google Scholar 

  2. V. A. Gilyarov, N. A. Tikhonina, V. N. Andrianov, Yu. T. Struchkov, and M. I. Kabachnik, Zh. Obshch. Khim.,48, 732 (1978).

    Google Scholar 

  3. J. Bellan, J. F. Brazier, N. Zenati, and M. Sanchez, Compt. Rend.,289, C449 (1979).

    Google Scholar 

  4. V. P. Kukhar', E. V. Grishkun, V. P. Rudaevskii, and V. A. Gilyarov, Zh. Obshch. Khim.,50, 1477 (1980).

    Google Scholar 

  5. É. S. Kozlov, Zh. Obshch. Khim.,50, 2425 (1980).

    Google Scholar 

  6. A. F. Grapov, N. N. Mel'nikov, and L. V. Razvodovskaya, Usp. Khim.,39, 39 (1970).

    Google Scholar 

  7. N. A. Tikhonina, G. I. Timofeeva, E. I. Matrosov, V. A. Gilyarov, and M. I. Kabachnik, Zh. Obshch. Khim.,45, 2414 (1975).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. M. Butlerov Chemical Institute of the V. I. Ul'yanov-Lenin Kazan State University, USSR

    B. A. Arbuzov, É. N. Dianova & E. Ya. Zabotina

Authors
  1. B. A. Arbuzov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. É. N. Dianova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. Ya. Zabotina
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2635–2638, November, 1981.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Arbuzov, B.A., Dianova, É.N. & Zabotina, E.Y. Reaction of 2-acetyl-3-methoxy-5-methyldiazaphospholine with p-toluenesulfonyl azide. Russ Chem Bull 30, 2192–2194 (1981). https://doi.org/10.1007/BF01094661

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01094661

Keywords

Search

Navigation