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Reactions of bis(trifluoromethyl)carbamoyl fluoride with nucleophilic reagents

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The easily leaving bis(trifluoromethyl)amino group is eliminated as a stable anion when nucleophilic reagents act on bis(trifluoromethyl)carbamoyl fluoride.

  2. 2.

    The similarity in the reactivity of bis(trifluoromethyl)carbamoyl fluoride and the perfluoro-2-azapropene dimer is due to the electronic analogy of the fluorocarbonyl and fluorotrifluoromethylimido groups.

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Literature cited

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. F. Gontar, É. G. Bykhovskaya, A. S. Vinogradov & I. L. Knunyants

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  1. A. F. Gontar
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  2. É. G. Bykhovskaya
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  3. A. S. Vinogradov
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  4. I. L. Knunyants
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2632–2635, November, 1981.

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Gontar, A.F., Bykhovskaya, É.G., Vinogradov, A.S. et al. Reactions of bis(trifluoromethyl)carbamoyl fluoride with nucleophilic reagents. Russ Chem Bull 30, 2188–2191 (1981). https://doi.org/10.1007/BF01094660

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  • DOI: https://doi.org/10.1007/BF01094660

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