Conclusions
We were the first to effect the enantioselective hydrogenation of a mixture of isomeric 2-phenylbutenes on chiral cobalt catalytic systems of the Ziegler-Natta type in an optical yield of ∼25%.
Literature cited
C. Carlini, D. Politi, and F. Ciardelli, Chem. Commun.,1970, 1260.
U. M. Dzhemilev, A. Z. Yakupova, and G. A. Tolstikov, Izv. Akad. Nauk SSSR, Ser. Khim.,1975, 2379.
S. H. Laurie, Austral. J. Chem.,20, 2597 (1967).
A. M. Aguiar, C. J. Morrow, and J. D. Morrison, J. Org. Chem.,41, 1545 (1976).
P. B. Harrison, J. Kenyon, and J. R. Shepherd, J. Chem. Soc.,1926, 658.
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2621–2622, November, 1981.
Rights and permissions
About this article
Cite this article
Nindakova, L.O., Shmidt, F.K., Klabunovskii, E.I. et al. Asymmetric hydrogenation on chiral cobalt complexes. Russ Chem Bull 30, 2177–2178 (1981). https://doi.org/10.1007/BF01094655
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01094655