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Reactions of olefins with elementary sulfur in the presence of triiron dodecacarbonyl

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Dithiolane diiron hexacarbonyl complexes are formed in the reaction of S8 with Fe3(CO)12 in the presence of cyclohexene or 1-hexene. When cyclohexene is used, sulfur atoms are incorporated at the double bond to give cyclic polysulfides.

  2. 2.

    The structure of thiotriiron decarbonyl was investigated by means of x-ray diffraction analysis.

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Literature cited

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    N. S. Nametkin, V. D. Tyurin, G. G. Aleksandrov, I. V. Petrosyan, B. I. Kolobkov, A. M. Krapivin & Yu. T. Struchkov

  2. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    N. S. Nametkin, V. D. Tyurin, G. G. Aleksandrov, I. V. Petrosyan, B. I. Kolobkov, A. M. Krapivin & Yu. T. Struchkov

Authors
  1. N. S. Nametkin
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  2. V. D. Tyurin
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  3. G. G. Aleksandrov
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  4. I. V. Petrosyan
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  5. B. I. Kolobkov
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  6. A. M. Krapivin
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  7. Yu. T. Struchkov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2572–2577, November, 1981.

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Nametkin, N.S., Tyurin, V.D., Aleksandrov, G.G. et al. Reactions of olefins with elementary sulfur in the presence of triiron dodecacarbonyl. Russ Chem Bull 30, 2133–2138 (1981). https://doi.org/10.1007/BF01094643

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  • DOI: https://doi.org/10.1007/BF01094643

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