Conclusions
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1.
In the carbonylation of propylene with carbon monoxide in the presence of ruthenium dodecacarbonyl, Ru3(CO)12, the solvent affects the yield and the isomeric composition of the product.
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2.
The addition of salts of Group I–III, VI, or VIII metals to Ru3(CO)12 affects the activity of the complex. The maximum yield of carbonylation products is obtained by adding MoCl5.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2532–2535, November, 1981.
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Lapidus, A.L., Gil'denberg, E.Z., Krasnova, L.L. et al. Carbonylation of propylene with carbon monoxide in the presence of Ru3(CO)12 catalysts. Russ Chem Bull 30, 2093–2096 (1981). https://doi.org/10.1007/BF01094637
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DOI: https://doi.org/10.1007/BF01094637