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Hydrogenation catalysis by palladium cluster complexes with phenanthroline

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The [(Pd5Phen2)OAc]n (I) cluster complex is formed through the reaction of palladium diacetal with molecular hydrogen in the presence of o-phenanthroline. A product of composition [Pd10Phen4(O2)3](OAc)2 separates out when this complex is treated with oxygen.

  2. 2.

    The hydrogenation of O2, 1,3-pentadiene, and allyl alcohol are catalyzed by aqueous solutions of (I).

  3. 3.

    The kinetic data on the hydrogenation of allyl alcohol by (I) in aqueous solution can be described by a mechanism involving complexing between cluster and substrate, reaction with hydrogen leading to the formation of the alcohol and regeneration of the original palladium compound. Rate constants have been determined for the various steps in this mechanism.

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Literature cited

  1. A. S. Berenblyum, G. V. Turkova, and I. I. Moiseev, Izv. Akad. Nauk SSSR, Ser. Khim., 514 (1981).

  2. A. S. Berenblyum, A. G. Knizhnik, S. L. Mund, and I. I. Moiseev, Izv. Akad. Nauk SSSR, Ser. Khim., 2175 (1979).

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow

    A. S. Berenblyum, S. L. Mund, T. P. Goranskaya & I. I. Moiseev

  2. Élektrogorsk Branch, All-Union Scientific-Research Institute for the Treatment of Petroleum, USSR

    A. S. Berenblyum, S. L. Mund, T. P. Goranskaya & I. I. Moiseev

Authors
  1. A. S. Berenblyum
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  2. S. L. Mund
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  3. T. P. Goranskaya
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  4. I. I. Moiseev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2472–2475, November, 1981.

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Berenblyum, A.S., Mund, S.L., Goranskaya, T.P. et al. Hydrogenation catalysis by palladium cluster complexes with phenanthroline. Russ Chem Bull 30, 2041–2044 (1981). https://doi.org/10.1007/BF01094624

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  • DOI: https://doi.org/10.1007/BF01094624

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