Conjugated heat and mass transfer between a reactive solid and a gas in the presence of nonequilibrium chemical reactions

Abstract

An investigation of a multicomponent boundary layer taking account of nonequilibrium chemical reactions has been made in a number of publications [1–3]; here, the temperature of the solid was assumed to be known or was determined from the condition of the conservation of energy at the interface between the gas and the solid, taking account of the solution of the equation of thermal conductivity in the solid phase. At the same time, heating of the material of a coating is an unavoidable step in any mechanism of thermokinetic decomposition and, in view of this, it is necessary to take account of the lag of the heat-transfer process inside the solid. Therefore, it is necessary to solve the equation of the energy balance in the solid phase simultaneously with the system of the equations of the boundary layer, i.e., the conjugate problem. The present article discusses the problem of flow around a solid in the vicinity of a frontal critical point, taking account of the dependence of the processes taking place in the solid body on the time, in the presence of two heterogeneous and one homogeneous reactions. The distributions of the velocity, the temperature, and the concentrations in the boundary layer are obtained, as well as the mass rate of entrainment of the material at different moments of time. The time of the change between kinetic and diffusion conditions of the course of the heterogeneous chemical reactions (the ignition time) is determined. It is established that, in the presence of a homogeneous chemical reaction, the mass rate of entrainment is less than with a frozen flow.