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Ferroelectric Curie points at perovskite-type oxides

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Abstract

The covalent bond energy of the A-O bonding and the enthalpy of formation for perovskite-type oxides ABO3 were found to show high correlations with Curie points. Perovskite-type titanates with a lower covalent bond energy show higher Curie points, while those with low standard enthalpy of formation show low Curie points, or do not cause displacive transitions. The standard enthalpy of formation of perovskite oxides was inferred to be approximately equal to the sum of that of simple oxides.

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Authors and Affiliations

  1. Department of Industrial Chemistry, Faculty of Engineering, University of Tokyo, Hongo 7-3-1, 113, Bunkyo-ku, Tokyo, Japan

    Kaoru Igarashi, Kunihito Koumoto & Hiroaki Yanagida

Authors
  1. Kaoru Igarashi
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  2. Kunihito Koumoto
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  3. Hiroaki Yanagida
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Igarashi, K., Koumoto, K. & Yanagida, H. Ferroelectric Curie points at perovskite-type oxides. J Mater Sci 22, 2828–2832 (1987). https://doi.org/10.1007/BF01086478

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  • DOI: https://doi.org/10.1007/BF01086478

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