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Effect of the viscosity of the stationary liquid phase on the broadening of the chromatographic zone

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    For an efficient use of the stationary liquid phase,its viscosity should not exceed a certain limiting value, which is independent of the nature of the liquid phase and is determined by the experimental conditions.

  2. 2.

    The limiting value of the viscosity of the stationary liquid phase can be estimated approximately from the equation δ2η=10−10g·cm/sec.

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Literature cited

  1. R. Kaiser, Gas-Chromatographie, Leipzig (1960).

  2. A. A. Zhukhovitskii and N. M. Turkel'taub, Gas Chromatography [in Russian], Gostoptekhizdat (1962).

  3. J. J. Duffield and L. B. Rogers, Analyt. Chem.,32, 340 (1960).

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  4. J. J. van Deemter, F. J. Zuiderweg, and A. Klinkenberg, Chem. Engng. Sci,5, 271 (1956).

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences, USSR

    V. G. Berezkin, V. R. Alishoev, S. N. Ershova & I. A. Tutorskii

Authors
  1. V. G. Berezkin
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  2. V. R. Alishoev
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  3. S. N. Ershova
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  4. I. A. Tutorskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1711–1712, September, 1965

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Berezkin, V.G., Alishoev, V.R., Ershova, S.N. et al. Effect of the viscosity of the stationary liquid phase on the broadening of the chromatographic zone. Russ Chem Bull 14, 1682–1683 (1965). https://doi.org/10.1007/BF01083834

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  • DOI: https://doi.org/10.1007/BF01083834

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