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Production of isoprene from formaldehyde and isobutylene through 3-methylbutanediol-1,3

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A variation of the method of production of isoprene from formaldehyde and isobutylene through the intermediate stage of 3-methylbutanediol-1,3 is proposed.

  2. 2.

    Isoprene of a high degree of purity (99.5–99.8%) is produced in the process; few side products are formed.

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Literature cited

  1. É. Érandeil and L. A. Mikeshka, Uspekhi Khimii,23, 223 (1954); M. I. Farberov, Ya. I. Rotshtein, A. M. Kut'in, and N. K. Shemyakina, Zh. Obshch. Khimii,27, 2806 (1957); K. M. Trenke and M. S. Nemtsov, Zh. Prikl. Khimii,36, 1595 (1963).

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  2. L. Kh. Freidlin, V. Z. Sharf, G. I. Samokhvalov, M. A. Miropol'skaya, I. M. Privalova, and M. Ts. Yanotovskii, Neftekhimiya,3, 104 (1963).

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  3. C. C. Price, Mechanism of Reactions of Carbon, Carbon Double Bonds, Interscience Publisher, New York (1946), p. 45.

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Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    V. Z. Sharf, L. Kh. Freidlin, G. K. Oparina, V. I. Kheifets, M. K. Bychkova, G. M. Kopylevich & V. V. Yakubenok

  2. Experimental Design Office of Synthetic Products, Priokskii Sovnarkhoz, Tula

    V. Z. Sharf, L. Kh. Freidlin, G. K. Oparina, V. I. Kheifets, M. K. Bychkova, G. M. Kopylevich & V. V. Yakubenok

Authors
  1. V. Z. Sharf
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  2. L. Kh. Freidlin
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  3. G. K. Oparina
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  4. V. I. Kheifets
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  5. M. K. Bychkova
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  6. G. M. Kopylevich
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  7. V. V. Yakubenok
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1663–1665, September, 1965

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Sharf, V.Z., Freidlin, L.K., Oparina, G.K. et al. Production of isoprene from formaldehyde and isobutylene through 3-methylbutanediol-1,3. Russ Chem Bull 14, 1621–1623 (1965). https://doi.org/10.1007/BF01083812

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  • DOI: https://doi.org/10.1007/BF01083812

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