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Action of phosphorous esters on perfluoro gem-chloronitroso compounds

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The action of triethyl phosphite or diethyl hydrogen phosphite on perfluoro gem-chloronitroso compounds leads to anhydrides of diethyl hydrogen phosphate with the corresponding fluorinated oximes.

  2. 2.

    Data were obtained which support a reaction mechanism in which the initial attack of phosphite is on the nitrogen atom of the nitroso group.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences, USSR

    A. A. Gevorkyan, B. L. Dyatkin & I. L. Knunyants

Authors
  1. A. A. Gevorkyan
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  2. B. L. Dyatkin
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  3. I. L. Knunyants
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Additional information

This article is published in accordance with a resolution of the Conference of Chief Editors of Journals of the Academy of Sciences of the USSR of July 12, 1962, as a dissertation paper by A. A. Gevorkyan.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1599–1606, September, 1965

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Gevorkyan, A.A., Dyatkin, B.L. & Knunyants, I.L. Action of phosphorous esters on perfluoro gem-chloronitroso compounds. Russ Chem Bull 14, 1563–1569 (1965). https://doi.org/10.1007/BF01083798

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  • DOI: https://doi.org/10.1007/BF01083798

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