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Catalytic hydrogenation of tetrahydrodioxo-(dihydroanthrylene)-triptycene

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The kinetics of the hydrogenation of 12,13,14,15-tetrahydro-12,15-dioxo-13,14; 9,10-(9′,10′)-dihydroanthrylene)triptycene [1] on 1% Pd on charcoal was investigated in dioxane medium at atmospheric pressure.

  2. 2.

    The dependence of the reaction rate on the initial concentration of (I), the amount of the catalyst, and the reaction temperature (25–60°) was found.

  3. 3.

    The activation energy, equal to 7.7 kcal/mole, was determined from the temperature dependence of the reaction rate constant.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    R. Yu. Mamed-Zade, E. I. Klabunovskii & A. A. Balandin

Authors
  1. R. Yu. Mamed-Zade
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  2. E. I. Klabunovskii
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  3. A. A. Balandin
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Additional information

The article is published on the basis of a resolution of the Conference of Editors-in-Chief of the Journals of the Academy of Sciences, USSR, of July 12, 1962, as the dissertation work of R. Yu. Mamed-Zade.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1570–1575, September, 1965

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Mamed-Zade, R.Y., Klabunovskii, E.I. & Balandin, A.A. Catalytic hydrogenation of tetrahydrodioxo-(dihydroanthrylene)-triptycene. Russ Chem Bull 14, 1536–1540 (1965). https://doi.org/10.1007/BF01083794

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  • DOI: https://doi.org/10.1007/BF01083794

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