Summary
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1.
The total acidity of iron phosphate, equal to 0.10–0.15 mequiv/g, was determined.
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2.
The alkylation of benzene, toluene, ethylbenzene, isopropylbenzene, chlorobenzene, and phenol with sec- and tert-monoalkyl halides was conducted in the presence of iron orthophosphate. The isomeric monoalkylaryls were isolated in yields from 38 to 73% of the theoretical. Dialkyl derivatives (up to 3%) were isolated only in the alkylation of benzene.
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A. A. Balandin, A. I. Kukina, and N. E. Malenberg, Izv. AN SSSR. Otd. Khim. N.,1962, 574.
L. Kh. Freidlin, V. Z. Sharf, M. A. Abidov, and V. T. Glukhovtsev, Izv. AN SSSR, Otd. Khim. N.,1963, 1824.
A. F. Plate and O. A. Shcherbakova, Neftekhimiya,4, 507 (1963).
A. D. Petrov, M. A. Chel'tsova, and M. I. Batuev, Izv. AN SSSR. Otd. Khim. N.,1951, 571.
I. Turkevich and R. K. Smith, J. Chem. Phys.,16, 466 (1948).
V. Zharkova and B. Moldavskii, Zh. Obshch. Khimii,17, 1268 (1947).
N. D. Zelinskii and Yu. A. Arbuzov, Dokl. AN SSSR,23, 793 (1939).
I. A. Shatenshtein, Problems of Chemical Kinetics, Catalysis, and Reactivity [in Russian], Izd. AN SSSR, Moscow (1955), p. 699.
I. V. Gostunskaya, N. 1. Tyun'kina, and B. A. Kazanskii, Izv. AN SSSR, Otd. Khim. N.,1960, 132.
L. Wright and S. Weller, J. Amer. Chem. Soc.,76, 5305 (1954).
L. Bateman, L. Y. Guneen, and I. A. Lyons, J. Chem. Soc.,1951, 2290.
I. P. Tsukervanik, Investigations in the Field of Alkylation of the Nucleus of Aromatic Compounds, Transactions of Chemical Science [in Russian], Book 8, Erevan (1955).
N. V. Rudenko, Dissertation [in Russian], Moscow (1959).
N. I. Shuikin and N. A. Pozdnyak, Izv. AN SSSR. Otd. Khim. N.,1961, 373.
É. A. Karakhanov, Dissertation [in Russian], Moscow (1963).
H. Pines and L. A. Shaap, Advances in Catalysis,12 (1961).
I. P. Tsukervanik, Kh. Kim, and A. S. Kurbatova, Zh. Obshch. Khimii,33, 234 (1963).
N. G. Sidorova, Zh. Obshch. Khimii,22, 962 (1952).
K. V. Topchieva and E. N. Rosolovskaya, Neftekhimiya,2, 298 (1962).
A. A. Balandin, M. B. Turova-Polyak, A. E. Agronomov, I. M. Khorlina, and L. S. Kon'kova, Dokl. AN SSSR,114, 173 (1957).
K. Kearby, “Actes 2-e Congr. internat. catalyse”, Paris,2 (1962).
L. Bellamy, Infrared Spectra of Molecules [Russian translation], IL, Moscow (1957).
E. P. Babin and A. A. Kolpakchi, Kinetika i Kataliz,3, 855 (1962).
V. Tambovtseva and I. Tsukervanik, Zh. Obshch. Khimii,9, 820 (1945).
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The article is published on the basis of a resolution of the Conference of Editors-in-Chief of the Journals of the Academy of Sciences, USSR, of July 12, 1962, as the dissertation work of N. E. Malenberg.
The authors would like to take this opportunity to thank E. N. Rossolovskaya and L. D. Ashkinadze for their consultation and aid in the work.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1565–1570, September, 1965
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Malenberg, N.E., Balandin, A.A. & Kukina, A.I. Catalytic properties of iron orthophosphate. Communication 2. Alkylation of benzene, its homologs and derivatives. Russ Chem Bull 14, 1531–1535 (1965). https://doi.org/10.1007/BF01083793
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DOI: https://doi.org/10.1007/BF01083793