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Kinetics of the oxidation of aqueous solutions of glyceraldehyde by molecular oxygen

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The kinetic principles of the oxidation of glyceraldehyde in aqueous solution were discussed.

  2. 2.

    The accelerating action of a catalyst (copper acetate) and the inhibiting effect of inhibitors of free radical processes on the oxidation of glyceraldehyde in aqueous solution were detected, indicating a chain character of this reaction.

  3. 3.

    Chemiluminescence is observed in aqueous solutions of glyceraldehyde in the presence of oxygen. The rate of generation of chains and the length of the chain, equal to three units, were determined by chemiluminescent methods.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences, USSR

    L. M. Andronov, Z. K. Maizus & N. M. Émanuél'

Authors
  1. L. M. Andronov
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  2. Z. K. Maizus
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  3. N. M. Émanuél'
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1519–1523, September, 1965

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Andronov, L.M., Maizus, Z.K. & Émanuél', N.M. Kinetics of the oxidation of aqueous solutions of glyceraldehyde by molecular oxygen. Russ Chem Bull 14, 1489–1492 (1965). https://doi.org/10.1007/BF01083786

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  • DOI: https://doi.org/10.1007/BF01083786

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