Abstract
In the absence of zincate, silicate ion was found to have favourable effects on the corrosion rate of zinc powder in alkaline solution, as expressed by its gassing rate and polarization curve. The addition of zincate lessened the effect of silicate. Glass corrosion and silicate-zincate interaction in alkaline solution are also emphasized.
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D. P. Gregory, P. C. Jones and D. P. Redfearn,J. Electrochem. Soc. 119 (1972) 1288.
R. N. Snyder and J. J. Lander,Electrochem, Technol. 3 (1965) 161.
P. Ruetschi,J. Electrochem. Soc. 114 (1967) 301.
T. P. Dirkse and R. Timmer,116 (1969) 162.
L. Binder and K. Kordesch,J. Electroanal. Chem. 180 (1984) 495.
E. A. Shumaker, in ‘The Primary Battery’, Vol. I, (edited by G. H. Heise and N. C. Cahoon), John Wiley & Sons, New York (1971) p. 181.
J. S. Drury, N. A. Hampson and A. Marshall,J. Electroanal. Chem. 50 (1974) 292.
R. D. Armstrong and M. F. Bell,Electrochim. Acta 21 (1976) 155.
P. C. Morgan, N. A. Hampson and D. J. Spiers,Surf. Technol. 12 (1981) 245.
J. M. Gras and J. J. Le Coz, Proceedings of the 2nd World Hydrogen Energy Conference, Zurich (1978) pp. 255–77.
A. E. Avrushchenko, B. N. Yanchuk, N. V. Korovin and L. G. Ganichenko,Electrokhimiya 22 (1986) 1258.
J. W. Mellor, ‘A comprehensive treatise on inorganic and theoretical chemistry’, Vol. III, Longmans, Green and Co., New York (1947).
W. Ertel, ‘The physical-chemistry of the silicates’, University of Chicago Press, Chicago (1954) p. 1364.
I. M. Kolthoff, E. B. Sandell, E. J. Meehan and S. Bruchenstein, ‘Quantitative Chemical Analysis’ (4th ed.), Macmillan, London (1969) p. 452.
R. A. Sharma,J. Electrochem. Soc. 135 (1988) 1996.
J. Hendrikx, A. Van Der Putten, W. Visscher and E. Barendrecht,Electrochim. Acta 29 (1984) 81.
D. P. Boden, R. B. Wylie and V. J. Spera,J. Electrochem. Soc. 118 (1971) 1298.
R. W. Powers,J. Electrochem. Soc. 118 (1971) 685.
Y. Pointud, J. Juillard, J. P. Morel and L. Avedikian,Electrochim. Acta 19 (1974) 229.
S. U. Falk and A. J. Salkind, ‘Alkaline storage batteries’, John Wiley & Sons, New York (1969) Chap. 8.
F. Mansfeld and S. Gilman,J. Electrochem. Soc. 117 (1970) 1328.
L. M. Baugh, F. L. Tye and N. C. White,Power Sources 9 (1983) 303.
T. S. Lee,J. Electrochem. Soc. 118 (1971) 1278.
R. Renaud and J.-Y. Huot, in preparation.
R. Breault, Production d'hydrogène en milieu alcalin: influence des silicates et des ions dihypoferrites. Thesis, University of Sherbrooke (1982).
L. Brossard and J.-Y. Huot,J. Appl. Electrochem. 19 (1989) 882.
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Huot, J.Y. The effects of silicate ion on the corrosion of zinc powder in alkaline solutions. J Appl Electrochem 22, 443–447 (1992). https://doi.org/10.1007/BF01077547
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DOI: https://doi.org/10.1007/BF01077547