Summary
Capto-dative substituents determine the ease of selective hydrogen abstraction but steric factors and the nature of the dehydrogenating agent influence the relative “radical scale”. This study underlines the preparative value of dehydrodimerisations. This method allows in addition the preparation of oligomers and polymers. A continuation of this work will be published in the near future.
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Naarmann, H., Beaujean, M., Merényi, R. et al. Dimerisation and oligomerisation by dehydrogenation as a general synthetic principle (1a) part II. Polymer Bulletin 2, 417–425 (1980). https://doi.org/10.1007/BF01064373
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DOI: https://doi.org/10.1007/BF01064373