Skip to main content
SpringerLink
Log in

Organoinorganic sulfonated polymers—Review

  • Published:
Journal of Inorganic and Organometallic Polymers Aims and scope Submit manuscript

Abstract

Polyphosphazenes and metal phosphonates have offered better opportunities than other organoinorganic polymers as starting polymers for the synthesis of sulfonated derivatives. Sulfonated organic polymers are well established in many technological applications and are covered by several literature reviews. Organoinorganic sulfonated polymers are rather new and have never been considered as a self-standing class. Yet since ion-containing polymers and organoinorganic polymers are expanding research fields, organoinorganic sulfonated polymers are likely to attain more attention in the future. The present review therefore covers the synthesis, structure, and properties of sulfonated polyphosphazenes and sulfonated metal phosphonates, in order to indicate what may be expected from organoinorganic polymers functionalized in this fashion.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. L. Albright and P. A. Yarnell,in Encyclopedia of Polymer Science and Engineering, 2nd ed., J. I. Kroschwiz, ed. (John Wiley and Sons, New York, 1987), Vol. 8, pp. 341–393.

    Google Scholar 

  2. R. D. Lundberg, inEncyclopecha of Polymer Science and Engineering, 2nd ed., J. I. Kroschwitz, ed. (John Wiley and Sons, New York, 1987). Vol. 8, pp. 393–423.

    Google Scholar 

  3. A. Duda and S. Penezek, inEncyclopecha of Polymer Science and Engeneering. 2nd ed., J. I. Kroschwitz, ed. (John Wiley & Sons, New York, 1989). Vol. 16. pp. 246–368.

    Google Scholar 

  4. E. Montoneri, G. Modica, L. Giuffré, L. Peraldo Bicelli, and S. Maffi.Int. J. Polym. Mater. 11, 263 (1987).

    Google Scholar 

  5. E. G. Kuntz,Chemtech 570 (1987).

  6. S. K. Bahador,Marcomol. Chem. Macromol. Symp. 37, 129 (1990).

    Google Scholar 

  7. R. B. Moore and C. R. Martin,Anal. Chem. 58, 2569 (1986).

    Google Scholar 

  8. W. Y. Hsu and T. D. Gierke,J. Membr. Sci. 13, 307 (1983).

    Google Scholar 

  9. G. Modica, L. Giuffre, E. Montoneri, V. Pozzi, and E. Tempesti.Int. J. Hydrogen Energy 8, 419 (1983).

    Google Scholar 

  10. E. Montoneri,J. Appl. Electrochem. 18, 280 (1988).

    Google Scholar 

  11. L. Breitbach, F. Hinke, and F. Staude,Angewandte Makromol. Chem. 184, 183 (1991).

    Google Scholar 

  12. A. Noshay and M. Robeson,J. Appl. Polym. Sci. 20, 1885 (1976).

    Google Scholar 

  13. C. Bailly, D. J. Williams, E. K. Karasz, and W. J. MacKnight,Polymer 28, 1009 (1987).

    Google Scholar 

  14. B. Zhang and R. A. Weiss,J. Polym Sci. Polym. Chem. 30, 91 (1992).

    Google Scholar 

  15. A. O. Patil, Y. Ikenoue, E. Wudl and A. J. Heeger.J. Am. Chem. Soc. 109, 1858 (1987).

    Google Scholar 

  16. G. Maneeke and W. Storek, inEncyclopedia of Polymer Science and Engineering. 2nd ed., J. I. Kroschwits, ed. (John Wiley & Sons, New York, 1986), Vol. 5. pp. 725–755.

    Google Scholar 

  17. P. Trefonas, inEncyclopedia of Poltmer Science and Engineering, 2nd ed., J. I. Krowschwits, ed. (John Wiley & Sons, New York, 1988), Vol. 13, pp. 163–187.

    Google Scholar 

  18. H. R. Allcock, inEncyclopedia of Polymer Science and Engineering. 2nd ed., J. I. Krowschwits, ed. (John Wiley & Sons, New York, 1988). Vol. 13. pp. 31–41.

    Google Scholar 

  19. A. Cleartield.Comments Inorg. Chem. 10, 89 (1990).

    Google Scholar 

  20. R. H. Neilson, R. Hani, P. Wisian-Neilson, J. J. Meister, A. K. Roy, and G. L. Hagnauer.Macromolecules 20, 910 (1987).

    Google Scholar 

  21. M. C. Gallazzi, E. Montoneri, P. Savarino, I. Bianchi, and L. Di Landro.J. Mater. Sci. Lett. 12, 436 (1993).

    Google Scholar 

  22. M. Kojima, J. H. Magill, M. Cypryk, M. I. White, U. Franz, and K. Matyjaszewski,Macromol. Chem. Phys. 195, 1823 (1994).

    Google Scholar 

  23. E. Montoneri, M. Gleria, G. Rieca, and G. C. Pappalardo,Makromol. Chem. 190, 191 (1989).

    Google Scholar 

  24. E. Montoneri, M. Gleria, G. Ricca, and G. C. Pappalardo,J. Makromol. Sci. Chem. A 26, 645 (1989).

    Google Scholar 

  25. E. Montoneri, P. Savarino, M. C. Gallazzi, M. Gleria, and E. Minto.J. Inorg. Organomet. Polym. 2, 421 (1992).

    Google Scholar 

  26. H. R. Allcock, R. J. Fitzpatrick, and I. Salvati.Chem. Mater. 3, 1120 (1991).

    Google Scholar 

  27. E. Montoneri, G. Ricca, M. Gleria, and M. C. Gallazzi.Inorg. Chem. 30, 150 (1991).

    Google Scholar 

  28. E. Motoneri,J. Polym. Sci. A Polym. Chem. 27, 3043 (1989).

    Google Scholar 

  29. S. Ganapathiappan, K. Chen, and D. E. Shriver.Macromolecules 21, 2301 (1988).

    Google Scholar 

  30. H. R. Hallcock, F. H. Klingenberg, and M. E. Welker,Macromolecules 26, 5512 (1993).

    Google Scholar 

  31. S. V. Meille, A. Farina, and M. C. Gallazzi,Macromol. Rapid Commun. 15, 573 (1994).

    Google Scholar 

  32. G. Cao, V. M. Lynch, J. S. Swinnea, and I. E. Mallouk,Inorg. Chem. 29, 2112 (1990).

    Google Scholar 

  33. G. Cao and E. Mallouk.Inorg. Chem. 30, 1434 (1991).

    Google Scholar 

  34. E. J. Kosnie, E. I. McClymont, R. A. Hodder, and P. J. Squattrito.Inorg. Chim. Acta 201, 143 (1992).

    Google Scholar 

  35. A. Clearfield and U. Costantino, inComprechensive Supramolecular Chemistry, G. Alberti and T. Bein, eds. (Pergamon, Elsevier Science, New York, 1996), Vol. 7, Chap. 4.

    Google Scholar 

  36. D. M. Poojary, B. Zhang, and A. Clearfield,Angew. Chem. Int. Ed. Eng. 33, 2324 (1994)

    Google Scholar 

  37. D. M. Poojary, B. Zhang, and A. Clearfield,J. Chem. Soc. Dalton Trans. 2453 (1994).

  38. G. Alberti,Iec. Chem. Res. 11, 163 (1978).

    Google Scholar 

  39. D. M. Poojary, H. L. Hu, E. Campbell, and A. Clearfield.Acta Crystallogr. B 42 996 (1993).

    Google Scholar 

  40. A. Clearfield and J. A. Stynes.J. Inorg. Nucl. Chem. 26, 117 (1964).

    Google Scholar 

  41. G. Alberti and E. Torracca,J. Inorg. Nucl. Chem. 30, 317 (1968).

    Google Scholar 

  42. A. Christensen, E. K. Andersen, I. G. K. Andersen, G. Alberti, N. Nielsen and M. S. Lehmann.Acta Chem. Scand. 44, 865 (1990).

    Google Scholar 

  43. G. Alberti, M. Casciola, R. Vivani, and R. K. Biswas.Inorg. Chem. 32, 4600 (1993).

    Google Scholar 

  44. M. B. Dines, P. M. D. Giacomo, P. K. Callahan, P. C. Griffith, R. H. Lane, and R. E. Cooksey.ACS Symp. Ser. 192, 223 (1982).

    Google Scholar 

  45. G. Alberti, U. Costantino, E. Marmottini, R. Vivani, and P. Zappelli.Angew. Chem. Int. Ed. Engl. 32, 1357 (1993).

    Google Scholar 

  46. G. Alberti, S. Murcia Mascaros, and R. Vivani,Mater. Chem. Phys. 35, 187 (1993).

    Google Scholar 

  47. C. Y. Yang and A. Clearfield,React. Polym. 5, 13 (1987).

    Google Scholar 

  48. E. W. Stein, A. Clearfield, and M. A. Subramanian.Solid State Ion. 83, 113 (1996).

    Google Scholar 

  49. P. M. Digiacomo and M. B. Dines.Polyhedron 1, 61 (1982).

    Google Scholar 

  50. M. Curini, O. Rosati, E. Pisani, and U. Costantino,Syn. Lett. (in press).

  51. G. Alberti, M. Casciola, U. Constantino, A. Peraio, and E. Montoncri,Solid State Ion. 50, 315 (1992).

    Google Scholar 

  52. G. Alberti, M. Casciola, R. Palombari, and A. Peraio.Solid State Ion. 58, 339 (1992).

    Google Scholar 

  53. G. Alberti, E. Boccali, M. Casciola, E. Massinelli, and E. Montoneri,Solid State Ion. (in press).

  54. E. W. Stein, C. Bhardwaj, C. Y. Ortiz-Villa, A. Clearfield, and M. Subramaian, inMat. Sci. Forum. J. Rouxel, M. Tourmaux, and R. Brec, eds. (Trans Tech., Switzerland. 1994), Vol. 152–153, p. 115.

    Google Scholar 

  55. T. C. Chang, W. Y. Shen, and S. H. Ho,Micropor. Mater 4, 335 (1995).

    Google Scholar 

  56. E. Montoneri, P. Savarino, E. Adani, and G. Ricca.Phosphorus Sulphur and Silicon 106. 37 (1995).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Dipartimento di Chimica Generale e Organica Applicata, Universita di Torino, Corso Massimo D'Azeglio 48, 10125, Torino, Italy

    E. Montoneri

  2. Dipartimento di Chimica, Universita di Perugia, Via Elce di Sotto 8, 06123, Perugia, Italy

    M. Casciola

Authors
  1. E. Montoneri
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Casciola
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Montoneri, E., Casciola, M. Organoinorganic sulfonated polymers—Review. J Inorg Organomet Polym 6, 301–312 (1996). https://doi.org/10.1007/BF01062511

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01062511

Key Words

Search

Navigation