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Synthesis and study of block copolymers based on caprolactam and polyethylene glycol

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Abstract

High-molecular-weight block copolymers of polycaproamide and polyethylene glycol were synthesized and are distinguished by the different size of the polyamide block and number of polyamide and polyethylene oxide blocks in the macromolecule. In the conditions of synthesis of the copolymers used. their molecular characteristics are in good agreement with the calculated characteristics, and the melting point is a linear function of the reciprocal of the average degree of polymerization of the polyamide block in the copolymer. An opinion was advanced concerning the expedient regions of practical use of block copolymers differing in the ratio of stiff (polyamide) and flexible (polyethylene oxide) blocks.

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References

  1. T. S. Usacheva, Reaction of Amines and Polycaproamide with Epichlorohydrin in Alcohol Medium, Candidate Dissertation, Ivanovo Institute of Chemical Engineering, Ivanovo (1982).

    Google Scholar 

  2. L. N. Mizerovskii, Yu. S. Paikachev, et al., Vysokomolek. Soedin.,A13, No. 5, 1109–1113 (1971).

    Google Scholar 

  3. S. L. Dobychin, F. N. Stolyarova, et al., Zav. Lab.,37, No. 7, 779–781 (1971).

    Google Scholar 

  4. G. Reinish and U. Gol'ke, Vysokomolek. Soedin.A15, 372–378 (1973).

    Google Scholar 

  5. L. N. Mizerovskii, Yu. S. Paikachev, et al., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol.,15, 1034–1037 (1972).

    Google Scholar 

  6. N. V. Sholichev, Use of H3PO4 to Accelerate Hydrolytic Polymeriaation of Caprolactam in Continuously Operating Equipment, Candidate Dissertation, IICE, Ivanovo (1975).

    Google Scholar 

  7. Kh. Kozert, Synthesis and Study of Block Copolymers of Polycaproamide and Polyethylene Glycols, Candidate Dissertation, IICE, Ivanovo (1991).

    Google Scholar 

  8. L. N. Mizerovskii, Yu. M. Bazarov, et al., Vysokomolek. Soedin.,A16, No. 12, 2780–2786 (1974).

    Google Scholar 

  9. H. K. Reimschussel, J. Polym. Sci.,41, 457–461 (1959).

    Google Scholar 

  10. L. N. Mizerovskii, A. K. Kuznetsov, et al., Vysokomolek. Soedin.,A24, No. 16, 1174–1179 (1982).

    Google Scholar 

  11. R. L. Miller and L. E. Nilsen, J. Polym. Sci.,44, 391–394 (1960).

    Google Scholar 

  12. L. S. Kalinina, M. A. Motorina, et al., Analysis of Condensation Polymers [in Russian], Khimiya, Moscow (1984).

    Google Scholar 

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Authors
  1. V. G. Silant'eva
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  2. N. A. Filatova
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  3. L. N. Mizerovskii
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Additional information

Ivanovo State Academy of chemical Engineering. Translated from Khimicheskie Volokna, No. 4, pp. 55–57, July–August, 1996.

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Silant'eva, V.G., Filatova, N.A. & Mizerovskii, L.N. Synthesis and study of block copolymers based on caprolactam and polyethylene glycol. Fibre Chem 28, 278–281 (1996). https://doi.org/10.1007/BF01060147

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  • DOI: https://doi.org/10.1007/BF01060147

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