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Acyclic diene metathesis (ADMET) oligomerization of divinyltetramethyldisiloxane in the presence of rhodium and ruthenium complexes

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Abstract

Acyclic diene metathesis (ADMET) polymerization of divinyltetramethyldisiloxane in the presence of rhodium [RhCl(COD)]2 and ruthenium RuCl2(PPh3)3 catalysts led predominantly to linear oligomers [M n=1815,M w/M n=1.16] if the rhodium catalyst was used or to mixtures of dimeric and trimeric oligomers if the ruthenium complex was applied. The rhodium complex appeared to be the first effective catalyst for ADMET polymerization of divinyldisubstituted organosilicon compounds.

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References

  1. K. B. Wagener, J. M. Boncella, J. G. Nel, R. P. Duttweiler, and M. Hillmyer,Makromol. Chem. 191, 365 (1990).

    Google Scholar 

  2. K. B. Wagener and K. Brzezinska,Macromolecules 24, 5273 (1991).

    Google Scholar 

  3. K. B. Wagener, J. M. Boncella, and J. G. Nel,Macromolecules 24, 2649 (1991).

    Google Scholar 

  4. K. B. Wagener and D. W. Smith Jr.,Macromolecules 24, 6073 (1991).

    Google Scholar 

  5. D. W. Smith and K. B. Wagener,Macromolecules 26, 1633 (1993).

    Google Scholar 

  6. E. Sh. Finkel'shtein, E. B. Portnykh, I. V. Antipova, and B. M. Vdovin,Izv. Akad. Nauk. SSSR Ser. Khim. 1358 (1989).

  7. E. Sh. Finkel'shtein, N. N. Ushakov, and E. B. Portnykh,J. Mol. Catal. 76, 133 (1992).

    Google Scholar 

  8. E. Sh. Finkel'shtein and B. Marciniec, in B. Marciniec, and J. Chojnowski (eds.,Progress in Organosilicon Chemistry (Gordon & Breach, Langhorne, 1995), p. 445.

    Google Scholar 

  9. D. W. Smith and K. B. Wagener,J. Polym. Preprints 33, 112 (1992).

    Google Scholar 

  10. B. Marciniec and J. Gulinski,J. Organometal. Chem. 266, C19 (1984).

    Google Scholar 

  11. B. Marciniec, L. Rzejak, J. Gulinski, Z. Foltynowicz, and W. Urbaniak,J. Mol. Catal. 46, 329 (1988).

    Google Scholar 

  12. B. Marciniec, Z. Foltynowicz, C. Pietraszuk, J. Gulinski, and H. Maciejewski,J. Mol. Catal. 90, 213 (1994).

    Google Scholar 

  13. B. Marciniec, inOrganosilicon and Bioorganosilicon Chemistry, H. Sakurai, ed. (Ellis Horwod, New York, 1984), Chap. 17.

    Google Scholar 

  14. G. Giordano and R. H. Craptree,Inorg. Synth. 13, 218 (1971).

    Google Scholar 

  15. P. S. Hallman, T. A. Stephenson, and G. Wilkinson,Inorg. Synth. 12, 237 (1970).

    Google Scholar 

  16. B. Marciniec, C. Pietraszuk, and Z. Foltynowicz,J. Organometal. Chem. 474, 83 (1994).

    Google Scholar 

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Authors and Affiliations

  1. Department of Organometallic Chemistry, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780, Poznan, Poland

    Bogdan Marciniec & Mariusz Lewandowski

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  1. Bogdan Marciniec
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  2. Mariusz Lewandowski
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Additional information

Part 14 in the series “Metathesis of Silicon-Containing Olefins”: for Part 13, see Ref. 8.

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Marciniec, B., Lewandowski, M. Acyclic diene metathesis (ADMET) oligomerization of divinyltetramethyldisiloxane in the presence of rhodium and ruthenium complexes. J Inorg Organomet Polym 5, 115–122 (1995). https://doi.org/10.1007/BF01058140

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  • DOI: https://doi.org/10.1007/BF01058140

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