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Effect of Cr, Co, and Ti additions on the high-temperature oxidation behavior of Ni3Al

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Abstract

The oxidation behavior of Ni3Al+2.90 wt.% Cr, Ni3Al+3.35 wt% Co, and Ni3Al+2.99 wt.% Ti alloys was studied in 1 atm of air at 1000, 1100, and 1200°C. Isothermal tests revealed parabolic kinetics for all three alloys at all temperatures. Cyclic oxidation for 28 two-hour cycles produced little spallation at 1000°C, but caused partial spallation at 1100°C. Especially, at 1200°C severe spallation in all three alloys was observed. Although additions of Cr, Co, or Ti to Ni3Al alloys slightly increased the isothermal-oxidation resistance, the additions tended to decrease the cyclic-oxidation resistance. The major difference in the oxidation of the three alloys compared with the oxidation of pure Ni3Al alloys was the existence of small α-Al2O3 particles in the middle of the α-Al2O3 scale and the formation of irregularly shaped Kirkendall voids at the alloy-scale interface.

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Authors and Affiliations

  1. Department of Metallurgical Engineering, Sung-Kyun-Kwan University, 440-746, Suwon, South Korea

    S. C. Choi, H. J. Cho & D. B. Lee

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  1. S. C. Choi
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  2. H. J. Cho
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  3. D. B. Lee
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Choi, S.C., Cho, H.J. & Lee, D.B. Effect of Cr, Co, and Ti additions on the high-temperature oxidation behavior of Ni3Al. Oxid Met 46, 109–127 (1996). https://doi.org/10.1007/BF01046886

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  • DOI: https://doi.org/10.1007/BF01046886

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