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A study on the oxidation characteristics of cast irons containing aluminum

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Abstract

Isothermal-oxidation characteristics of cast irons containing aluminum (5–15% Al) from 700 to 1000°C in air have been studied. In addition to massgain measurements, the morphology and composition of the oxide scales have been examined by SEM-EDX system and XRD analysis. A normal Fe−5Al−C alloy does not develop protective, adherent scales. Even the addition of misch metal and calcium silicide to such an alloy does not improve its oxidation resistance. But aluminum cast iron develops considerable oxidation resistance only when a sufficient quantity of silicon is also present in the alloy. Treatment of the alloy with misch, metal and calcium silicide together assists in protective scale formation. Among the alloys investigated Fe−15Al−Si−C treated with misch metal and calcium silicide shows minimum oxidation at 1000°C.

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References

  1. Jun Takada, Sadahiro Yamamoto, Shiomi Kikuchi, and Masao Adachi,Oxid. Met. 25, 93 (1986).

    Google Scholar 

  2. H. A. Ahmed, R. P. Underhill, W. W. Smeltzer, M. E. Brett, and M. J. Graham,Oxid. Met. 28, 347 (1987).

    Google Scholar 

  3. P. J. Smith, R. M. Beauprie, W. W. Smeltzer, D. V. Stevanovic, and D. A. Thompson,Oxid. Met. 28, 259 (1987).

    Google Scholar 

  4. C. Sykes and J. W. Bampfylde,JISI 130, 389 (1934).

    Google Scholar 

  5. R. Presscott and M. J. Graham,Oxid. Met. 38, 73 (1992).

    Google Scholar 

  6. C. G. Mckamy and C. T. Liu,Scripta Met. 24, 2119 (1990).

    Google Scholar 

  7. E. U. Petitbon and J. F. Wallace,AFS Cast Met. Res. J. 9, 127 (1973).

    Google Scholar 

  8. S. L. Case and K. R. Vanhorn,Aluminum in Iron and Steel (Wiley, New York, 1953).

    Google Scholar 

  9. W. Justusson, V. F. Zackay, and E. R. Morgan,Trans. ASM 49, 905 (1957).

    Google Scholar 

  10. C. H. Kao and C. M. Wan,J. Mater. Sci. 23, 894 (1988).

    Google Scholar 

  11. W. W. Webb, J. T. Norton, and C. Wagner,J. Electrochem. Soc. 103, 112 (1956).

    Google Scholar 

  12. C. Pelhan,AFS Cast Met. Res. J. 66 (1972).

  13. W. E. Boggs,Oxid. Met. 10, 277 (1976).

    Google Scholar 

  14. S. Guruswamy, J. P. Hirth, and G. W. Powell,Oxid. Met. 19, 77 (1983).

    Google Scholar 

  15. A. Prodhan, Ph.D. thesis, I.I.T. Kharagpur, 1988.

  16. C. Wagner,Corros. Sci. 5, 751 (1965).

    Google Scholar 

  17. C. Pelhan,The Metallurgy of Cast Iron, (Georgi Publ. Switzerland, 1975), p. 841.

    Google Scholar 

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Ghosh, S., Prodhan, A., Mohanty, O.N. et al. A study on the oxidation characteristics of cast irons containing aluminum. Oxid Met 45, 109–131 (1996). https://doi.org/10.1007/BF01046822

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  • DOI: https://doi.org/10.1007/BF01046822

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