Abstract
A few complexes of copper(II) have been prepared by reacting copper(II) acetate with salicylidene methyl anthranilates in alcohol medium. Analytical data indicate 1 : 2 stoichiometry. These copper(II) complexes show normal magnetic moments indicating no spin interactions. With the help of electronic and infrared spectral evidences it has been suggested that in these complexes copper(II) exhibits coordination number six.
Similar content being viewed by others
Literatur
L. Sacconi, Coord. Chem. Rev.1, 126, 192 (1966); b)R. H. Holm, G. W. Everette, Jr., undA. Chakravorthy, Progr. Inorg. Chem.7, 83 (1966); c)S. Yamada, E. Ohno, Y. Kuge, A. Takeuchi, K. Yamanouchi undK. Twasaki, Coord. Chem. Rev.3, 247 (1968) d)B. O. West, New Pathways in Inorganic Chemistry, S. 303. Cambridge: University Press. 1968 e)M. Calligaris, G. Nardin undL. Randaccio, Coord. Chem. Rev.7, 385 (1972).
A. V. Ablov undN. V. Gerbeleu, Russ. J. Inorg. Chem.9, 46 (1964);10, 33, 624 (1965) b)A. V. Ablov, N. V. Gerbeleu undB. T. Oloi, Russ. J. Inorg. Chem.15, 1405, 1622 (1970);16, 99, 379 (1971) c)A. V. Ablov, N. V. Gerbeleu undM. V. Shopron, Russ. J. Inorg. Chem.16, 386, 932 (1971);15, 963 (1970) d)A. V. Ablov, N. I. Belichuk undL. N. Nazhelskaya, Russ. J. Inorg. Chem.17, 226 (1972) e)A. V. Ablov undN. V. Gerbeleu, Russ. J. Inorg. Chem.9, 1260 (1964) f)C. C. Lee, A. Syamal undL. J. Theriot, Inorg. Chem.10, 1669 (1971) g)W. E. Hatfield undL. F. Bunger, Inorg. Chem.5, 1161 (1966) h)H. Preut, F. Huber, H. J. Haupt, R. Cetalu undR. Barbieri, Z. Anorg. allgem. Chem.410, 88 (1974) i)J. G. Mohanty, S. Baral, R. P. Singh undA. Chakravorthy, Inorg. Nucl. Chem. Letts.10, 665 (1974).
A. D. Toy, M. D. Hobday, P. D. W. Boyel undJ. D. Smith undJ. R. Pilbrow, J. Chem. Soc. [Dalton]1973, 1259.
R. C. Paul, S. K. Vasista, S. K. Mehra undD. Singh, Mat. Chem.106, 1375 (1975) und dort zitierte Literatur.
G. T. Morgan undF. H. Brustall, J. Chem. Soc.1937, 1649;1938, 1672 b)F. Lions undK. V. Martin, J. Amer. Chem. Soc.79, 2733 (1957)75, 3834 (1953) c)M. R. Litzow, L. F. Power undA. M. Tait, Austral. J. Chem.24, 899 (1971) d)F. Lions undK. V. Martin, J. Amer. Chem. Soc.88, 2733 (1957) e)W. J. Stratton undD. H. Busch, J. Amer. Chem. Soc.82, 4834 (1960);80, 3191 (1958).
J. C. Duff, J. Chem. Soc.1941, 547.
F. A. Cotton undg. Wilkinson, Advanced Inorganic Chemistry. Wiley Eastern Pvt. 1969.
B. N. Figgis, Introduction to Ligand Fields. London: Interscience. 1969.
P. W. Anderson, Phys. Rev.79, 350 (1950).
A. P. Ginsberg, Inorg. Chim. Acta. Reviews5, 45 (1971).
T. M. Dunn, Some Aspects of Crystal Field Theory (T. M. Dunn, D. S. McClure undR. G. Pearson, Hrsg.), S. 38, New York: Harper and Row. Tokyo: John Weatherhill. 1965.
L. Sacconi undM. Ciampolini, J. Chem. Soc.1964, 276.
E. J. Halbert, Austral. J. Chem.28, 313 (1975).
J. Lewis, Y. C. Lin, R. K. Royston undR. C. Thompson, J. Chem. Soc.1965, 6464.
I. G. Ross, M. L. Tonnet undS. Yamada, Trans. Faraday Soc.60, 840 (1964).
P. Teyssie undJ. J. Charette, Spectrochim. Acta19, 1407 (1963).
H. H. Freedman, J. Amer. Chem. Soc.83, 2900 (1961).
A. W. Baker undA. T. Shulgin, J. Amer. Chem. Soc.81, 1523 (1959);80, 5358 (1958).
K. C. Melhotra undS. M. Shehagal, Indian J. Chem.13, 153 (1975); 599 (1975); b)J. Michel undR. A. Walton, J. Inorg. Nucl. Chem.37, 71 (1975).
A. E. Kovacic, Spectrochim. Acta23 A, 183 (1967).
C. P. Prabhakaran undC. C. Patel, J. Inorg. Nucl. Chem.31, 3316 (1969); b)B. C. Sharma undC. C. Patel, Indian J. Chem.8, 747 (1970); c)N. S. Biradar undV. H. Kulkarni, J. Inorg. Nucl. Chem.33, 3847 (1971); d)N. S. Biradar, V. H. Kulkarni undN. N. Sirmokadam, J. Inorg. Nucl. Chem.34, 3657 (1972); e)N. S. Biradar, V. B. Mahale undV. H. Kulkarni, Inorg. Chim. Acta7, 267 (1973).
K. Nakamoto undA. E. Martell, J. Chem. Phys.32, 583 (1960); b)K. Nakamoto, P. J. McCarthy, A. Ruby undA. E. Martell, J. Amer. Chem. Soc.83, 1066 (1961); c)K. Nakamoto, P. J. McCarthy undA. E. Martell, J. Amer. Chem. Soc.83, 1272 (1961); d)G. T. Behnke undK. Nakamoto, Inorg. Chem.6, 433 (1967); e)R. C. Fay undT. J. Pinnavia, Inorg. Chem.7, 508 (1968); f)R. W. Jones undR. C. Fay, Inorg. Chem.12, 2599 (1973); g)N. S. Biradar undV. H. Kulkarni, Z. Anorg. Allg. Chem.387, 275 (1972); h)N. S. Biradar undA. L. Locker, J. Inorg. Nucl. Chem.36, 1915 (1974).
D. K. Jonson, H. J. Stoklosa undJ. R. Wasson, J. Inorg. Nucl. Chem.37, 1397 (1975).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kulkarni, V.H., Prabhakar, B.K. & Patil, B.R. Kupfer(II)-Komplexe mit monofunktionellen dreizähnigenSchiffbasen mit O,N,O-Sequenzen. Monatshefte für Chemie 108, 1305–1312 (1977). https://doi.org/10.1007/BF01046444
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF01046444